No.109
Chiral Reducing Reagents
| C1615 | (-)-B-Chlorodiisopinocampheyl- borane (ca.65% in n-Hexane) (1a) |
100ml |
| C1614 | (+)-B-Chlorodiisopinocampheyl- borane (ca.65% in n-Hexane) (1b) |
100ml |

References
1) Asymmetric reduction of aryl alkyl ketones and aliphatic ketones
a) H. C. Brown, J. Chandrasekharan, P. V. Ramachandran, J. Am.C hem. Soc., 110, 1539 (1988).
b) idem, J. Org. Chem., 51, 3394 (1986).
c)J. Chandrasekharan, P. V. Ramachandran,H. C. Brown, ibid., 50, 5446 (1985).
2) Asymmetric reduction of hindered acetylenic ketones
P. V. Ramachandran, A. V. Teodorovic, M. V . Rangaishenvi, H. C. Brown, J. Org. Chem., 57, 2379 (1992).
3) Asymmetric reduction of fluoro ketones
P. V. Ramachandran, A. V. Teodorovic, H. C. Brown, Tetrahedron, 49, 1725 (1993).
4) Asymmetric reduction of acylsilanes
J. D. Buynak, J. B. Strickland, T. Hurd, A. Phan, J. Chem. Soc., Chem. Commun., 1989, 89.
5) A highly enantioselective synthesis of both optical isomers of the antidepressant drugs
M. Srebnic, P. V. Ramachandran, H. C. Brown, J. Org. Chem., 53, 2916 (1988).
a) H. C. Brown, J. Chandrasekharan, P. V. Ramachandran, J. Am.C hem. Soc., 110, 1539 (1988).
b) idem, J. Org. Chem., 51, 3394 (1986).
c)J. Chandrasekharan, P. V. Ramachandran,H. C. Brown, ibid., 50, 5446 (1985).
2) Asymmetric reduction of hindered acetylenic ketones
P. V. Ramachandran, A. V. Teodorovic, M. V . Rangaishenvi, H. C. Brown, J. Org. Chem., 57, 2379 (1992).
3) Asymmetric reduction of fluoro ketones
P. V. Ramachandran, A. V. Teodorovic, H. C. Brown, Tetrahedron, 49, 1725 (1993).
4) Asymmetric reduction of acylsilanes
J. D. Buynak, J. B. Strickland, T. Hurd, A. Phan, J. Chem. Soc., Chem. Commun., 1989, 89.
5) A highly enantioselective synthesis of both optical isomers of the antidepressant drugs
M. Srebnic, P. V. Ramachandran, H. C. Brown, J. Org. Chem., 53, 2916 (1988).
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