No.98
Hydrozirconation
| Z0010 | Zirconocene Chloride Hydride (Schwartz's Reagent) |
1g |
References
1) Synthesis and rearrangement of alkylzirconium(IV) complexes
a) Reaction of the complexes with electrophiles
D. W. Hart, J. Schwartz, J. Am. Chem. Soc., 96, 8115 (1974).
b) Oxidation of the complexes to alcohols
T. F. Blackburn, J. A. Labinger, J. Schwartz, Tetrahedron Lett., 1975, 3041.
c) Oxidative homologation of olefins via CO insertion into C-Zr bond
C. A. Bertelo, J. Schwartz, J. Am. Chem. Soc., 97, 228 (1975).
2) Stereospecific and regioselective functionalization of alkylacetylenes
D. W. Hart, T. F. Blackburn, J. Schwartz, J. Am. Chem. Soc., 97, 679 (1975).
3) Other applications
a) Synthesis of long-chain primary alkyl compounds
T. Gibson, L. Tulich, J. Org. Chem., 46, 1821 (1981).
b) Conversion of alkynes and alkenes into one-carbon homologated aldehydes
E. Negishi, D. R. Swanson, S. R. Miller, Tetrahedron Lett., 29, 1631 (1988).
a) Reaction of the complexes with electrophiles
D. W. Hart, J. Schwartz, J. Am. Chem. Soc., 96, 8115 (1974).
b) Oxidation of the complexes to alcohols
T. F. Blackburn, J. A. Labinger, J. Schwartz, Tetrahedron Lett., 1975, 3041.
c) Oxidative homologation of olefins via CO insertion into C-Zr bond
C. A. Bertelo, J. Schwartz, J. Am. Chem. Soc., 97, 228 (1975).
2) Stereospecific and regioselective functionalization of alkylacetylenes
D. W. Hart, T. F. Blackburn, J. Schwartz, J. Am. Chem. Soc., 97, 679 (1975).
3) Other applications
a) Synthesis of long-chain primary alkyl compounds
T. Gibson, L. Tulich, J. Org. Chem., 46, 1821 (1981).
b) Conversion of alkynes and alkenes into one-carbon homologated aldehydes
E. Negishi, D. R. Swanson, S. R. Miller, Tetrahedron Lett., 29, 1631 (1988).
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