N-Fluoro-N'-(chloromethyl)triethylenediamine Bis(tetrafluoroborate)

Synonym : 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate)

Certificate of Analysis

About Lot Numbers

MSDS[PDF]

General Information

TCI Product No. :

F0358

Stock Status :

Status at 03:00 a.m. on Mar 19, 2010

* Items available from stock in Japan will be delivered in 10 business days

Purity / Analysis Method :

>90.0%(T)

Storage :

M.F. / M.W. :

C7H14B2ClF9N2=354.26

CAS Number :

140681-55-6

Related CAS Number :

MDL Number :

MFCD00142607

Application
Regioselective Fluorohydroxylation Reaction of Arylallenes C. Zhou, J. Li, B. Lu, C. Fu, S. Ma, Org. Lett., 2008, 10, 581. Regiospecific fluorination of functionalized phenols Typical procedue: To 4-(biphenyl)tributylstananne (44.3 mg) in acetone (2.0 mL) at 23ºC is added silver triflate (51.4 mg) and N-fluoro-N'-(chloromethyl)triethylenediamine bis(tetrafluoroborate) (F-TEDA-BF4) (42.5 mg). The reaction mixture is stirred for 20 min at 23ºC and then concentrated in vacuo. The residue is purified by preparative TLC eluting with hexane to give 12.0 mg of the fluorinated compound as colorless solid (70% yield). T. Furuya, A. E. Strom, T. Ritter, J. Am. Chem. Soc. 2009, 131, 1662.

References
Merck Index(14) :	8425

Informative Links
TCI Product Literature :	Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds[PDF]
Related Categories :	Structure of Chemicals B (Classes of Boron Compounds) Tetrafluoroborates Synthetic Organic Chemistry Fluorinating Reagents, Building Blocks & Fluorinated Bioactive Compounds Fluorinating Reagents Electrophilic Fluorinating Reagents Synthetic Organic Chemistry Halogenation Fluorination Structure of Chemicals Quaternary Ammonium Compounds Ammonium Polyhalides, etc. (Quaternary)