Structure
| TCI Product No. : | B2027 | ||||||||||||||||||
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| Stock Status : |
Status at 03:00 a.m. on Mar 19, 2010 * Items available from stock in Japan will be delivered in 10 business days |
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| Purity / Analysis Method : | >96.0%(T) | ||||||||||||||||||
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| M.F. / M.W. : | C34H28FeP2=554.38 | ||||||||||||||||||
| CAS Number : | 12150-46-8 | ||||||||||||||||||
| Related CAS Number : | |||||||||||||||||||
| MDL Number : | MFCD00001422 | ||||||||||||||||||
Synthesis of Carbinols Typical procedure: Under an air atmosphere, a Schlenk tube is charged with Cu(OAc)2•H2O (4.0 mg, 0.02 mmol), dppf (16.6 mg, 0.03 mmol), arylboronic acid (0.4 mmol), aldehyde (0.2 mmol), NaOAc (49.2 mg, 0.6 mmol), and toluene (3 mL) under ice-salt (-20 ºC). The mixture is stirred for 0.5 h at room temperature, refluxed for 24 h, and then cooled in a Schlenk tube to room temperature. The mixture is extracted with ethyl acetate (4×5 mL), and the organic layers are washed with water. The organic layers are dried over MgSO4, concentrated, and purified by flash column chromatography on silica gel to give the desired product. |
| TCI MAIL : | |
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| TCI Product Literature : | |
| Related Categories : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Fe (Iron) Compounds
Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Phosphine Ligands (for Suzuki-Miyaura Cross-coupling) Structure of Chemicals Metallocenes Ferrocenes Synthetic Organic Chemistry Phosphines Synthetic Organic Chemistry Phosphine Ligands |